Dynamic Nuclear Polarization in Silicon Microparticles

We report record high Si-29 spin polarization obtained using dynamic nuclear polarization in microcrystalline silicon powder. Unpaired electrons in this silicon powder are due to dangling bonds in the amorphous region of this intrinsically heterogeneous sample. Si-29 nuclei in the amorphous region become polarized by forced electron-nuclear spin flips driven by off-resonant microwave radiation while nuclei in the crystalline region are polarized by spin diffusion across crystalline boundaries. Hyperpolarized silicon microparticles have long T1 relaxation times and could be used as tracers for magnetic resonance imaging.Comment: 4 pages, 5 figures, published versio

Extended Debye Model for Molecular Magnets

Heat capacity data on Mn12 are fitted within the extended Debye model that takes into account a continuum of optical modes as well as three different speeds of sound.Comment: 4 Phys. Rev pages, 4 figures, submitted to Physical Review B as a Brief Report. In version 3 speeds of sound correcte

Nuclear-spin relaxation of 207^{207}Pb in ferroelectric powders

Motivated by a recent proposal by O. P. Sushkov and co-workers to search for a P,T-violating Schiff moment of the $^{207}$Pb nucleus in a ferroelectric solid, we have carried out a high-field nuclear magnetic resonance study of the longitudinal and transverse spin relaxation of the lead nuclei from room temperature down to 10 K for powder samples of lead titanate (PT), lead zirconium titanate (PZT), and a PT monocrystal. For all powder samples and independently of temperature, transverse relaxation times were found to be $T_2\approx 1.5$ms, while the longitudinal relaxation times exhibited a temperature dependence, with $T_1$ of over an hour at the lowest temperatures, decreasing to $T_1\approx 7$s at room temperature. At high temperatures, the observed behavior is consistent with a two-phonon Raman process, while in the low temperature limit, the relaxation appears to be dominated by a single-phonon (direct) process involving magnetic impurities. This is the first study of temperature-dependent nuclear-spin relaxation in PT and PZT ferroelectrics at such low temperatures. We discuss the implications of the results for the Schiff-moment search.Comment: 6 pages, 4 figure

Magnetically Hidden Order of Kramers Doublets in d1d^1 Systems: Sr2_2VO4_4

We formulate and study an effective Hamiltonian for low-energy Kramers doublets of $d^1$-ions on a square lattice. We find that the system exhibits a magnetically hidden order in which the expectation values of the local spin and orbital moments both vanish. The order parameter responsible for a time-reversal symmetry breaking has a composite nature and is a spin-orbital analog of a magnetic octupole. We argue that such a hidden order is realized in the layered perovskite Sr$_2$VO$_4$.Comment: 4 pages, 3 figures; minor change

Emission of gamma rays shifted from resonant absorption by electron-nuclear double transitions in ^{151}Eu^{2+}:CaF_2

We show that the emission of a gamma-ray photon by a nucleus can be influenced by a microwave magnetic field acting on the atomic electrons. We study theoretically these electron-nuclear double transitions (ENDTs) for ^{151}Eu nuclei in a CaF_2 lattice at low temperature, in the presence of a static magnetic field and of a microwave magnetic field. The ENDTs acquire a significant intensity for certain resonance frequencies. The ENDTs are of interest for the identification of the position of the lines in complex M\"{o}ssbauer spectra.Comment: 8 pages; 3 Postscript figures: Fig. 1, Fig. 2(a), Fig. 2(b

Phonon bottleneck in the low-excitation limit

The phonon-bottleneck problem in the relaxation of two-level systems (spins) via direct phonon processes is considered numerically in the weak-excitation limit where the Schroedinger equation for the spin-phonon system simplifies. The solution for the relaxing spin excitation p(t), emitted phonons n_k(t), etc. is obtained in terms of the exact many-body eigenstates. In the absence of phonon damping Gamma_{ph} and inhomogeneous broadening, p(t) approaches the bottleneck plateau p_\infty > 0 with strongly damped oscillations, the frequency being related to the spin-phonon splitting Delta at the avoided crossing. For any Gamma_{ph} > 0 one has p(t) -> 0 but in the case of strong bottleneck the spin relaxation rate is much smaller than Gamma_{ph} and p(t) is nonexponential. Inhomogeneous broadening exceeding Delta partially alleviates the bottleneck and removes oscillations of p(t). The line width of emitted phonons, as well as Delta, increase with the strength of the bottleneck, i.e., with the concentration of spins.Comment: 16 PR pages, 14 Figure captions, submitted to PRB. The whole text does dot fit here. Please, get the correct file from http://www.lehman.edu/faculty/dgaranin/Bottleneck2.pd

Quantum irreversible decoherence behaviour in open quantum systems with few degrees of freedom. Application to 1H NMR reversion experiments in nematic liquid crystals

An experimental study of NMR spin decoherence in nematic liquid crystals (LC) is presented. Decoherence dynamics can be put in evidence by means of refocusing experiments of the dipolar interactions. The experimental technique used in this work is based on the MREV8 pulse sequence. The aim of the work is to detect the main features of the Irreversible Quantum Decoherence (IQD) in LC, on the basis of the theory presented by the authors recently. The focus is laid on experimentally probing the eigen-selection process in the intermediate time scale, between quantum interference of a closed system and thermalization, as a signature of the IQD of the open quantum system, as well as on quantifying the effects of non-idealities as possible sources of signal decays which could mask the intrinsic IQD. In order to contrast experiment and theory, the theory was adapted to obtain the IQD function corresponding to the MREV8 reversion experiments. Non-idealities of the experimental setting are analysed in detail within this framework and their effects on the observed signal decay are numerically estimated. It is found that, though these non-idealities could in principle affect the evolution of the spin dynamics, their influence can be mitigated and they do not present the characteristic behavior of the IQD. As unique characteristic of the IQD, the experimental results clearly show the occurrence of eigen-selectivity in the intermediate timescale, in complete agreement with the theoretical predictions. We conclude that the eigen-selection effect is the fingerprint of IQD associated with a quantum open spin system in LC. Besides, these features of the results account for the quasi-equilibrium states of the spin system, which were observed previously in these mesophases, and lead to conclude that the quasi-equilibrium is a definite stage of the spin dynamics during its evolution towards equilibriu

NMR relaxation and resistivity from rattling phonons in pyrochlore superconductors

We calculate the temperature dependence of NMR relaxation rate and electrical resistivity for coupling to a local, strongly anharmonic phonon mode. We argue that the two-phonon Raman process is dominating NMR relaxation. Due to the strong anharmonicity of the phonon an unusual temperature dependence is found having a low temperature peak and becoming constant towards higher temperatures. The electrical resistivity is found to vary like T^2 at low temperatures and following a sqrt{T} behavior at high temperatures. Both results are in qualitative agreement with recent observations on beta-pyrochlore oxide superconductors.Comment: 4 pages, 4 figures; new version with some minor additional clarifications; accepted for publication in Phys. Rev. Let

The high probability state transfers and entanglements between different nodes of the homogeneous spin 1/2 chain in inhomogeneous external magnetic field

We consider the high probability state transfers and entanglements between different nodes of the spin-1/2 chains governed by the XXZ-Hamiltonian using the inhomogeneous stationary external magnetic field. Examples of three-, four-, ten- and twenty-node chains are represented. A variant of realization of the proper inhomogeneous magnetic field is discussed.Comment: 16 pages, 2 figure

Metal-insulator transition through a semi-Dirac point in oxide nanostructures: VO2_2 (001) layers confined within TiO2_2

Multilayer (TiO$_2$)$_m$/(VO$_2$)$_n$ nanostructures ($d^1$ - $d^0$ interfaces with no polar discontinuity) show a metal-insulator transition with respect to the VO$_2$ layer thickness in first principles calculations. For $n$ $\geq$ 5 layers, the system becomes metallic, while being insulating for $n$ = 1 and 2. The metal-insulator transition occurs through a semi-Dirac point phase for $n$ = 3 and 4, in which the Fermi surface is point-like and the electrons behave as massless along the zone diagonal in k-space and as massive fermions along the perpendicular direction. We provide an analysis of the evolution of the electronic structure through this unprecedented insulator-to-metal transition, and identify it as resulting from quantum confinement producing a non-intuitive orbital ordering on the V $d^1$ ions, rather than being a specific oxide interface effect. Spin-orbit coupling does not destroy the semi-Dirac point for the calculated ground state, where the spins are aligned along the rutile c-axis, but it does open a substantial gap if the spins lie in the basal plane.Comment: 9 pages, 8 figure